Structure cristalline du cyclotétraphosphate triple de lithium sodium et d'éthylène diammonium trihydrate NaLi[NH3(CH2)2NH3]P4O12.3H2O
Identifieur interne : 001516 ( Main/Exploration ); précédent : 001515; suivant : 001517Structure cristalline du cyclotétraphosphate triple de lithium sodium et d'éthylène diammonium trihydrate NaLi[NH3(CH2)2NH3]P4O12.3H2O
Auteurs : Mohamed Bdiri [Tunisie] ; Amor Jouini [Tunisie]Source :
- Journal of Solid State Chemistry [ 0022-4596 ] ; 1989.
Abstract
Abstract: Classical methods extensively used for the synthesis of inorganic condensed phosphates are known to give compounds that are intermediate between inorganic and organic. We prepared the title compound to examine the possibility of using, in this new field, the ion exchange resin method. The cyclotetraphosphate is the first condensed phosphate associated with the ethylenediammonium ion and mixed monovalent cations. We describe its chemical preparation and crystal structure. The orthorhombic unit cell has the following dimensions: a = 13.135(3) Å, b = 7.737(2) Å, c = 15.478(4) Å, V = 1573(2)Å3, Dm = 2.020 g/cm3, Dx = 1.951 g/cm3, μ = 0.297 mm−1, space group is Pcca with Z = 4. The crystal structure has been solved by using 2005 unique reflections with a final R value of 0.043 (Rw = 0.045). The principal feature of this compound lies in its linear atomic arrangement of the monovalent cations with different coordination polyhedra. The lithium cation is statistically distributed on two general positions with 0.5 occupancy, or moves very rapidly between these two positions. The P4O4−12 ring anion is located around the twofold axis. The cohesiveness and the stability of the crystal result from two kinds of weak hydrogen bonds: NH---O and O(W)H---O. The structure of this compound is compared to that of Na2[NH3(CH2)2NH3]P4O12.2H2O; half the sodium positions are occupied by lithium cations.
Url:
DOI: 10.1016/0022-4596(89)90185-0
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 001145
- to stream Istex, to step Curation: 000C71
- to stream Istex, to step Checkpoint: 000D07
- to stream Main, to step Merge: 001570
- to stream Main, to step Curation: 001516
Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="fr">Structure cristalline du cyclotétraphosphate triple de lithium sodium et d'éthylène diammonium trihydrate NaLi[NH3(CH2)2NH3]P4O12.3H2O</title>
<author><name sortKey="Bdiri, Mohamed" sort="Bdiri, Mohamed" uniqKey="Bdiri M" first="Mohamed" last="Bdiri">Mohamed Bdiri</name>
</author>
<author><name sortKey="Jouini, Amor" sort="Jouini, Amor" uniqKey="Jouini A" first="Amor" last="Jouini">Amor Jouini</name>
<affiliation><country>Tunisie</country>
<placeName><settlement type="city">Monastir</settlement>
<region type="region" nuts="2">Gouvernorat de Monastir</region>
</placeName>
<orgName type="university" n="3">Université de Monastir</orgName>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:4B9BB009614D297B5178C13AD6C97716DCAC156F</idno>
<date when="1989" year="1989">1989</date>
<idno type="doi">10.1016/0022-4596(89)90185-0</idno>
<idno type="url">https://api.istex.fr/document/4B9BB009614D297B5178C13AD6C97716DCAC156F/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">001145</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001145</idno>
<idno type="wicri:Area/Istex/Curation">000C71</idno>
<idno type="wicri:Area/Istex/Checkpoint">000D07</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000D07</idno>
<idno type="wicri:doubleKey">0022-4596:1989:Bdiri M:structure:cristalline:du</idno>
<idno type="wicri:Area/Main/Merge">001570</idno>
<idno type="wicri:Area/Main/Curation">001516</idno>
<idno type="wicri:Area/Main/Exploration">001516</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="fr">Structure cristalline du cyclotétraphosphate triple de lithium sodium et d'éthylène diammonium trihydrate NaLi[NH3(CH2)2NH3]P4O12.3H2O</title>
<author><name sortKey="Bdiri, Mohamed" sort="Bdiri, Mohamed" uniqKey="Bdiri M" first="Mohamed" last="Bdiri">Mohamed Bdiri</name>
<affiliation wicri:level="1"><country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de l'Etat Solide, Départment de Chimie, Faculté des Sciences de Monastir, 5000 Monastir</wicri:regionArea>
<wicri:noRegion>5000 Monastir</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Jouini, Amor" sort="Jouini, Amor" uniqKey="Jouini A" first="Amor" last="Jouini">Amor Jouini</name>
<affiliation wicri:level="1"><country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de l'Etat Solide, Départment de Chimie, Faculté des Sciences de Monastir, 5000 Monastir</wicri:regionArea>
<wicri:noRegion>5000 Monastir</wicri:noRegion>
<placeName><settlement type="city">Monastir</settlement>
<region type="region" nuts="2">Gouvernorat de Monastir</region>
</placeName>
<orgName type="university" n="3">Université de Monastir</orgName>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j">Journal of Solid State Chemistry</title>
<title level="j" type="abbrev">YJSSC</title>
<idno type="ISSN">0022-4596</idno>
<imprint><publisher>ELSEVIER</publisher>
<date type="published" when="1989">1989</date>
<biblScope unit="volume">83</biblScope>
<biblScope unit="issue">2</biblScope>
<biblScope unit="page" from="350">350</biblScope>
<biblScope unit="page" to="360">360</biblScope>
</imprint>
<idno type="ISSN">0022-4596</idno>
</series>
<idno type="istex">4B9BB009614D297B5178C13AD6C97716DCAC156F</idno>
<idno type="DOI">10.1016/0022-4596(89)90185-0</idno>
<idno type="PII">0022-4596(89)90185-0</idno>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">0022-4596</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass></textClass>
<langUsage><language ident="fr">fr</language>
</langUsage>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Abstract: Classical methods extensively used for the synthesis of inorganic condensed phosphates are known to give compounds that are intermediate between inorganic and organic. We prepared the title compound to examine the possibility of using, in this new field, the ion exchange resin method. The cyclotetraphosphate is the first condensed phosphate associated with the ethylenediammonium ion and mixed monovalent cations. We describe its chemical preparation and crystal structure. The orthorhombic unit cell has the following dimensions: a = 13.135(3) Å, b = 7.737(2) Å, c = 15.478(4) Å, V = 1573(2)Å3, Dm = 2.020 g/cm3, Dx = 1.951 g/cm3, μ = 0.297 mm−1, space group is Pcca with Z = 4. The crystal structure has been solved by using 2005 unique reflections with a final R value of 0.043 (Rw = 0.045). The principal feature of this compound lies in its linear atomic arrangement of the monovalent cations with different coordination polyhedra. The lithium cation is statistically distributed on two general positions with 0.5 occupancy, or moves very rapidly between these two positions. The P4O4−12 ring anion is located around the twofold axis. The cohesiveness and the stability of the crystal result from two kinds of weak hydrogen bonds: NH---O and O(W)H---O. The structure of this compound is compared to that of Na2[NH3(CH2)2NH3]P4O12.2H2O; half the sodium positions are occupied by lithium cations.</div>
</front>
</TEI>
<affiliations><list><country><li>Tunisie</li>
</country>
<region><li>Gouvernorat de Monastir</li>
</region>
<settlement><li>Monastir</li>
</settlement>
<orgName><li>Université de Monastir</li>
</orgName>
</list>
<tree><country name="Tunisie"><noRegion><name sortKey="Bdiri, Mohamed" sort="Bdiri, Mohamed" uniqKey="Bdiri M" first="Mohamed" last="Bdiri">Mohamed Bdiri</name>
</noRegion>
<name sortKey="Jouini, Amor" sort="Jouini, Amor" uniqKey="Jouini A" first="Amor" last="Jouini">Amor Jouini</name>
</country>
</tree>
</affiliations>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001516 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001516 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Terre |area= CobaltMaghrebV1 |flux= Main |étape= Exploration |type= RBID |clé= ISTEX:4B9BB009614D297B5178C13AD6C97716DCAC156F |texte= Structure cristalline du cyclotétraphosphate triple de lithium sodium et d'éthylène diammonium trihydrate NaLi[NH3(CH2)2NH3]P4O12.3H2O }}
This area was generated with Dilib version V0.6.32. |